The
halides are relatively simple salts, of which the best known
is common salt (halite). They consist of a halogen such as fluorine
(F), chlorine (Cl), and the much rarer bromine (Br) and iodine
(I) combined with an alkali metal. The halogens are present as
large negatively charged cations linked with a pure ionic bond
to a small metal positive cation such as sodium (Na) or calcium
(Ca). The ions behave like almost perfect spheres and consequenlty
adopt the highest possible packing configuration, called close
cubic packing. Many of these minerals therefore have isometric
(cubic) crystal structures.
These are soft minerals, many of them soluble
in water and many are very important economically. Because
of their solubility,
most Halides are found in environments associated with water.
For example in deposits of hydrothermal origin, near hot springs,
and most commonly, in evaporite deposits. However the high
solubility means that often the minerals are often washed away
when the
local aqueous environment changes. Consequently many species
are transient and therefore very rare. Even so, some like halite
are so abundant that they are common despite their solublity.