Twin Crystals are crystals of the same mineral species that grow
attached to each other at certain angles.
Twinning in Crystals
Sometimes
during the growth of a crystal, or if the crystal is subjected
to stress or temperature/pressure conditions different from
those under which it originally formed, two or more intergrown
crystals are formed in a symmetrical fashion. These symmetrical
intergrowths of crystals are called twinned crystals. Twinning
is important to recognize, because when it occurs, it is often
one of the most diagnostic features enabling identification
of the mineral.
What happens
is that lattice points in one crystal are shared as lattice
points in another crystal adding apparent symmetry to the crystal
pairs. Twinning, because it adds symmetry, never occurs in
relation to the existing symmetry of the crystal.
Symmetry Operations that Define Twinning
Because symmetry
is added to a crystal by twinning, twining can be defined by
the symmetry
operations that are involved.
These include:
Reflection across a mirror plane. The added mirror plane
would then be called a twin plane.
Rotation about an axis or line in the crystal. The added
rotation axis would then be called a twin axis.
Inversion through a point. The added center of symmetry would
then be called a twin center.
Twin Laws
Twin laws
are expressed as either form symbols to define twin planes
(i.e. {hkl}) or zone symbols to define the
direction
of twin axes (i.e. [hkl]).
The surface along which the lattice points are shared in twinned
crystals is called a composition surface.
If the twin law can be defined by a simple planar composition
surface, the twin plane is always parallel to a possible crystal
face and never parallel to an existing plane of symmetry (remember
that twinning adds symmetry).
If the twin law is a rotation axis, the composition surface
will be irregular, the twin axis will be perpendicular to a lattice
plane, but will never be an even-fold rotation axis of the existing
symmetry. For example twinning cannot occur on a new 2 fold axis
that is parallel to an existing 4-fold axis.
Types of Twinning
Another way of defining twinning breaks twins into two separate
types.
Contact
Twins - have a planar composition surface separating
2 individual crystals. These are usually defined by a twin
law that expresses a twin plane (i.e. an added mirror plane).
An example shown here is a crystal of orthoclase twinned
on the Braveno Law.
Penetration
Twins - have an irregular composition surface
separating 2 individual crystals. These are defined by a
twin center or twin axis. Shown here is a twinned crystal
of orthoclase twinned on the Carlsbad Law.
Contact twins can also occur as repeated or
multiple twins.
Polysynthetic
twins - the compositions surfaces are parallel to one another.
Plagioclase commonly shows
this type of twinning, called the Albite Twin Law. Such twinning
is one of the most diagnostic features of plagioclase.
Cyclical
twins - the composition surfaces are not parallel to one another.
Origin of Twinning
Twinning can originate in 3 different ways, as growth twins,
transformation twins, and glide or deformation twins.
Growth
Twins - When accidents occur during crystal growth
and a new crystal is added to the face of an already existing
crystal, twinning can occur if the new crystal shares lattice
points on the face of the existing crystal, but has an orientation
different from the original crystal. Such growth twins can
be contact twins or penetration
twins.
Transformation
Twins - Transformation twinning occurs when a preexisting
crystal undergoes a transformation due
to a change in pressure or temperature. This commonly occurs
in
minerals
that have different crystal structures and different
symmetry at different temperatures or pressures. When the temperature
or pressure is changed to that where a new crystal structure
and symmetry is stable, different parts of the crystal
become arranged in different symmetrical orientations, and
thus form
an intergrowth of one or more crystals. Dauphiné and
Brazil twinning in quartz commonly forms this way during
a decrease in temperature.
Similarly the combination
of albite twinning and pericline twinning in alkali feldspar
results when high temperature sanidine (monoclinic)
transforms to low temperature microcline (triclinic).
This type of twinning is only observed using the polarizing microscope,
and results in a "tartan" twinning pattern. When this
twinning pattern is observed with the microscope it is one of
the most
characteristic diagnostic properties for the identification of
microcline.
Deformation
Twins - During deformation atoms can be pushed out of place.
If this happens to produce a symmetrical arrangement, it produces
deformation twins. The mineral calcite can be easily twinned
in this way, producing polysynthetic twins