Radioactivity is the spontaneous decay or disintegration of an
unstable atomic nucleus of an atom of one element to produce one
or more new nuclides and the emission of radiation (energy). The
radioactive isotopes of potassium, strontium, thorium, uranium
and samarium (40K, 87Sr, 232Th, 238U, 235U, 247Sm) are geologically
important for absolute age dating and as a diagnostic tool. The
radioactivity of some uranium- and thorium-rich minerals is great
enough that it can be detected by a Geiger counter and is therefore
a diagnostic property. The radioactivity of these and other radioactive
minerals may also pose a health risk.
There are three mechanisms of radioactive decay:
alpha decay, beta decay and electron capture. Alpha decay results
in the emission of an alpha particle. The alpha particle (a)
is identical to
the nucleus of 4He (helium) atom and consists of
two protons and two neutrons. The decay of uranium -238 is
an example of alpha
decay. Alpha decay reduces the mass number of the nucleus by
four and the atomic number by two due to the loss of two protons
and two neutrons from the parent isotope.
238U => 234Th + a + g + Energy
Beta decay results in the emission of a beta particle (b). A
beta particle is equivalent to a negatively charged electron.
The beta particle is formed through the decay of a neutral neutron
particle into a positively charged proton.
87Rb => 87Sr + b- + Energy
Electron capture occurs when an orbital electron is captured
by the nucleus. The decay of potassium -40 to argon -4o occurs
through electron capture. The nuclear charge decreases by one
without any significant change in mass.